Molecular Structure of BENZENAMINE HYDROCHLORIDE (142-04-1):

EINECS: 205-519-8
IUPAC Name: aniline hydrochloride
Molecular Formula: C₆H₈ClN
Molecular Weight: 129.587420 g/mol
H-Bond Donor: 2
H-Bond Acceptor: 1
SMILES: C1=CC=C(C=C1)N.Cl
InChI: InChI=1S/C6H7N.ClH/c7-6-4-2-1-3-5-6;/h1-5H,7H2;1H
InChIKey: MMCPOSDMTGQNKG-UHFFFAOYSA-N
Flash Point: 70 °C
Boiling Point: 184.4 °C at 760 mmHg
Melting Point: 196-198 °C(lit.)
Enthalpy of Vaporization: 42.44 kJ/mol
Vapour Pressure: 0.733 mmHg at 25 °C
Sensitive: Hygroscopic
Stability: Stable. Incompatible with strong oxidizing agents, strong acids.
BRN: 3593823

IARC Cancer Review: Animal Limited Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man , 27 (1982),p. 39.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay Completed; Results Positive: rat NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-130 (1978). ; Results Negative: mouse NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-130 (1978). . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

The safety information of BENZENAMINE HYDROCHLORIDE (142-04-1):
Hazard Codes: T ,N
Risk Statements: 23/24/25-40-41-43-48/23/24/25-50-68
23/24/25: Toxic by inhalation, in contact with skin and if swallowed
40: Limited evidence of a carcinogenic effect
41: Risk of serious damage to eyes
43: May cause sensitization by skin contact
48/23/24/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
50: Very Toxic to aquatic organisms
68: Possible risk of irreversible effects
Safety Statements: 26-27-36/37/39-45-61-63
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27: Take off immediately all contaminated clothing
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
61: Avoid release to the environment. Refer to special instructions safety data sheet
63: In case of accident by inhalation, remove casualty to fresh air and keep at rest
RIDADR: UN 1548 6.1/PG 3
WGK Germany: 2
RTECS: CY0875000
HazardClass: 6.1
PackingGroup: III
HS Code: 29214100
F: 3-9
Suspected carcinogen with experimental carcinogenic and tumorigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. Experimental teratogenic effects. Human mutation data reported. A skin and eye irritant. Combustible when exposed to heat or flame. When heated to decomposition or on contact with acid or acid fumes, it emits highly toxic fumes of aniline and chlorine compounds. Reacts explosively with aniline at 240°C/7.6 bar. Can react vigorously with oxidizing materials. To fight fire, use water, CO₂, water mist or spray, dry chemical. See also ANILINE.

DOT Classification:  6.1; Label: KEEP AWAY FROM FOOD

 BENZENAMINE HYDROCHLORIDE (142-04-1) is an aromatic ammonium salt with the appearance of white - yellow - semi-transparent flakes. It is also called ANILINE HCL ; ANILINE HYDROCHLORIDE ; Anilinechlofide ; ANILINIUM CHLORIDE ; C.I. 76001 ; benzenamine hydrochloride ; anilinechloride ; chlorhydrated’aniline , etc. BENZENAMINE HYDROCHLORIDE (142-04-1) is used in some fields such as fine chemicals, food. It is also used as reagent for analysis of carbohydrates and food. BENZENAMINE HYDROCHLORIDE (142-04-1) can be prepared by the reaction of aniline with hydrochloric acid:
C₆H₅NH₂ + HCl → C₆H₅N+H₃Cl^-