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Antimony tribromide

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Name

Antimony tribromide

EINECS N/A
CAS No. 7789-61-9 Density g/cm3
PSA 0.00000 LogP 2.53680
Solubility decomposed by H2O; soluble dilute HCl, HBr [HAW93] [MER06] Melting Point 97oC
Formula Br3Sb Boiling Point °Cat760mmHg
Molecular Weight 361.462 Flash Point °C
Transport Information N/A Appearance N/A
Safety A poison. Corrosive to skin, eyes, and mucous membranes. Reaction with water liberates HBr and antimony trioxide. Can cause severe burns. See also ANTIMONY COMPOUNDS. Risk Codes 20/22-51/53
Molecular Structure Molecular Structure of 7789-61-9 (Antimony tribromide) Hazard Symbols Xn,N
Synonyms

Antimony tribromide;

Article Data 80

Antimony tribromide Synthetic route

7440-36-0

antimony

74-83-9

methyl bromide

A

54553-06-9

dibromo(methyl)stibine

B

149442-29-5

dimethyltribromostibine

C

7789-61-9

antimony(III) bromide

Conditions
ConditionsYield
With copper passing CH3Br over powdered Sb and copper (ratio 10:1) at 350°C; fractionation; boiling range from 120 to 130°C at 14 Torr;A 40%
B 38%
C 22%
With copper passing CH3Br over powdered Sb and copper (ratio 10:1) at 350°C; fractionation; boiling range from 120 to 130°C at 14 Torr;A 40%
B 38%
C 22%
7440-36-0

antimony

74-83-9

methyl bromide

A

54553-06-9

dibromo(methyl)stibine

B

7789-61-9

antimony(III) bromide

C

53234-94-9

dimethylantimony bromide

Conditions
ConditionsYield
With hydrogen heating of Sb and Cu powder on asbestos for 3 h at 350°C in H2, then introduction of CH3Br over 32 h;A n/a
B n/a
C 30%
With Cu powder/asbestos; H2 heating of Sb and Cu powder on asbestos for 3 h at 350°C in H2, then introduction of CH3Br over 32 h;A n/a
B n/a
C 30%
7440-36-0

antimony

7726-95-6

bromine

7439-98-7

molybdenum

A

molybdenum(IV) oxide

B

7789-61-9

antimony(III) bromide

Conditions
ConditionsYield
With water In neat (no solvent) vac.; chemical transport; heating (500-1000°C);
7440-36-0

antimony

7726-95-6

bromine

7789-61-9

antimony(III) bromide

Conditions
ConditionsYield
In tetrachloromethane
In neat (no solvent) ratio bromine:Sb 3:1, heating (500°C);
Sb putting into one branch of right-angle quartz ampoule, stoich. Br2 putting in second branch, Br2 solidifying (brine), evac. (ca. 1E-5 mm Hg),Br2 liquefying, Sb portions addn. to Br2, then heating to 140-150.degre e.C, cooling after reaction ceased; SbBr3 sublimation at 140-150°C in cooled part of reactor; elem. anal.;
In tetrachloromethane for 5h; Inert atmosphere; Reflux;

antimony(III) sulfide

7726-95-6

bromine

A

SbSBr

B

13172-31-1

disulphur dibromide

C

7789-61-9

antimony(III) bromide

Conditions
ConditionsYield
reaction at room temperature;;
normal temp.;;
normal temp.;;
reaction at room temperature;;

silver(I) bromide

SbBr2AlBr4

A

AgAlBr4

B

7789-61-9

antimony(III) bromide

Conditions
ConditionsYield
With aluminum tri-bromide
10025-91-9

antimony(III) chloride

7558-02-3

potassium bromide

7789-61-9

antimony(III) bromide

Conditions
ConditionsYield
byproducts: KCl;

antimony(III) sulfate

7647-15-6

sodium bromide

7789-61-9

antimony(III) bromide

Conditions
ConditionsYield
byproducts: Na2SO4;
7440-36-0

antimony

7789-61-9

antimony(III) bromide

Conditions
ConditionsYield
With hydrogen sulfide byproducts: H2; above 360°C;
With bromine at 230°C with the mixt. of Br2 and CO2;
With bromine In carbon disulfide excess of powdered Sb; shaking; at the beginning cooling with H2O; at the end 40-45 °C; filtering, crystn.;
7783-56-4

antimony(III) fluoride

7789-61-9

antimony(III) bromide

Conditions
ConditionsYield
With bromine
With Br2

Antimony tribromide Chemical Properties


IUPAC Name: tribromostibane
Molecular Weight: 361.472 g/mol
Molecular Formula: Br3Sb 
Melting Point: 97 °C 
Boiling Point: 280 °C
Density: 4.15 g/mL at 25 °C(lit.)
Appreance: yellow crystalline powder
Vapor pressure: 1 mmHg ( 94 °C)
Refractive index: 1.74 
Flash Point: 280 °C
Sensitive: moisture sensitive
Merck: 14.706 
EINECS: 232-179-8
Exact Mass: 359.656784
MonoIsotopic Mass: 357.658831
Heavy Atom Count: 4
Complexity: 8
InChIKey: RPJGYLSSECYURW-UHFFFAOYSA-K
Synonyms of Antimony tribromide (CAS NO.7789-61-9) : Antimonousbromide ; Antimonybromide(sbbr3) ; Antimonytribromide , solid; Antimonytribromide , solution; Stibine, tribromo- ; Tribromo-stibin ; Tribromostibine ; Tribromo-Stibine  

Antimony tribromide Uses

 Antimony tribromide (CAS NO.7789-61-9) is used to make other antimony compounds, in chemical analysis, and in dyeing. 

Antimony tribromide Consensus Reports

Antimony and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Antimony tribromide Safety Profile

A poison. Corrosive to skin, eyes, and mucous membranes. Reaction with water liberates HBr and antimony trioxide. Can cause severe burns. See also ANTIMONY COMPOUNDS

Hazard Codes: HarmfulXn, DangerousN
Risk Statements: 20/22-51/53
R20/22: Harmful by inhalation and if swallowed 
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements: 61 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets
RIDADR: UN 3260 8/PG 2
WGK Germany: 2
RTECS: CC4400000
HazardClass: 8
PackingGroup: II

Antimony tribromide Standards and Recommendations

OSHA PEL: TWA 0.5 mg(Sb)/m3
ACGIH TLV: TWA 0.5 mg(Sb)/m3
DOT Classification:  8; Label: Corrosive

Antimony tribromide Specification

General Description: Antimony tribromide (CAS NO.7789-61-9) is the yellow crystalline solid dissolved in hydrobromic acid. Antimony tribromide (CAS NO.7789-61-9) is decomposed by water giving an antimony oxide and hydrobromic acid.  Antimony tribromide (CAS NO.7789-61-9) is corrosive to metals and tissue.
Air & Water Reactions: Water slowly hydrolyzes antimony tribromide to form antimony (III) oxide and hydrobromic acid. The dry powdered oxide ignites on heating in air.
Reactivity: Profile Acidic salts, such as Antimony tribromide (CAS NO.7789-61-9) , are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
Health Hazard: Antimony tribromide (CAS NO.7789-61-9) is toxic; If people inhalate, ingest or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

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