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Barium chloride

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Name

Barium chloride

EINECS 233-788-1
CAS No. 10361-37-2 Density 3.856 g/cm3
PSA 0.00000 LogP 1.37900
Solubility soluble in methanol; insoluble in ethanol, ethyl acetate Melting Point 962 °C
Formula BaCl2 Boiling Point 1560oC
Molecular Weight 244.267 Flash Point N/A
Transport Information UN 1564 6.1/PG 2 Appearance white crystalline powder
Safety 45-36-26-36/37/39 Risk Codes 22-25-20-36/37/38-36/38
Molecular Structure Molecular Structure of 10361-37-2 (Barium chloride) Hazard Symbols ToxicT,HarmfulXn,IrritantXi
Synonyms

Barium dichloride;HSDB 2633;NSC 146181;NCI-C61074;Ba 0108E;CCRIS 2286;SBA 0108E;UNII-0VK51DA1T2;

 

Barium chloride Synthetic route

7647-01-0

hydrogenchloride

Ba(x)O(x)Zn(x)

A

10361-37-2

barium(II) chloride dihydrate

B

zinc(II) hydroxide

Conditions
ConditionsYield
In not given addition of HCl to a barium zincate-lye ppts. Zn(OH)2; filtration of Zn(OH)2; evaporation of the filtrate under obtaining of BaCl2*2H2O;;A 90%
B >99
In not given addition of HCl to a barium zincate-lye ppts. Zn(OH)2; filtration of Zn(OH)2; evaporation of the filtrate under obtaining of BaCl2*2H2O;;A 90%
B >99

barium chloride monohydrate

10361-37-2

barium(II) chloride dihydrate

Conditions
ConditionsYield
With H2O In neat (no solvent, gas phase) Kinetics;
7647-01-0

hydrogenchloride

barium carbonate

10361-37-2

barium(II) chloride dihydrate

Conditions
ConditionsYield
In hydrogenchloride reaction of BaCO3 with HCl forms BaCl2*2H2O;; product contains 98-99%;;
7647-01-0

hydrogenchloride

barium sulfide

7446-09-5

sulfur dioxide

10361-37-2

barium(II) chloride dihydrate

Conditions
ConditionsYield
In not given byproducts: S; passing of SO2 in a BaS-solution ppts. BaS2O3; BaS2O3 reacts with HCl under formation of BaCl2; filtration of the pptd. S; crystallisation of BaCl2*2H2O out of the filtrate;;
7647-01-0

hydrogenchloride

barium sulfide

10361-37-2

barium(II) chloride dihydrate

Conditions
ConditionsYield
In neat (no solvent) treatment of CaS with an acidic mother-lye; addition of gaseous HCl to the solution under pptn. of BaCl2*2H2O;; washing with H2O or dild. BaS-solution;;
In water addition of HCl to a BaS-solution until pH 5; neutralisation with addition of BaS-solution; filtration; evaporation of the solution; vac.-crystallisation forms BaCl2*2H2O;;
In neat (no solvent) treatment of CaS with an acidic mother-lye; addition of concd. HCl to the solution under pptn. of BaCl2*2H2O;; washing with H2O or dild. BaS-solution;;

barium sulfide

7786-30-3

magnesium chloride

A

magnesium hydroxide

B

10361-37-2

barium(II) chloride dihydrate

Conditions
ConditionsYield
In not given reaction of BaS-solutions with MgCl2-solution ppts. Mg(OH)2; filtration; crystallisation of BaCl2*2H2O out of the solution;; repptn.;;
7647-01-0

hydrogenchloride

uranyl nitrate hydrate

barium(II) chloride

10361-37-2

barium(II) chloride dihydrate

Conditions
ConditionsYield
In diethyl ether extraction of irridiated UO2(NO3)2*nH2O with ether; the formed aq. solution contains all decomposition products; seperation of the aq. solution; addition of BaCl2; pptn. of BaCl2*2H2O with 37% aq. HCl;; twice repptn.;;

barium(II) chloride

10361-37-2

barium(II) chloride dihydrate

Conditions
ConditionsYield
In water pptn. (HCl);
In water pptn. out of concd. aq. BaCl2-solution with addition of alcohol;;
In water pptn. (HCl);
7647-01-0

hydrogenchloride

ammonium diuranate

barium(II) chloride

10361-37-2

barium(II) chloride dihydrate

Conditions
ConditionsYield
In hydrogenchloride solving of irridiated (NH4)2U2O7 in 25% aq. HCl; addition of BaCl2 in a small amount of H2O; pptn. of BaCl2*2H2O with 37% aq. HCl; filtration on hardened filter;; washing of the ppt. with 25% aq. HCl; washing with alcohol;;

barium hydroxide octahydrate

7782-50-5

chlorine

A

barium hypochlorite

B

10361-37-2

barium(II) chloride dihydrate

Conditions
ConditionsYield
with dry chlorine; product with 29.93% active chlorine content;
with dry chlorine; product with 29.93% active chlorine content;

Barium chloride Consensus Reports

Reported in EPA TSCA Inventory. Barium chloride (CAS NO.10361-37-2) and its compounds are on the Community Right-To-Know List. EPA Genetic Toxicology Program.

Barium chloride Standards and Recommendations

OSHA PEL: TWA 0.5 mg(Ba)/m3
ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen
DFG MAK: 0.5 mg(Ba)/m3

Barium chloride Specification

Barium chloride is the ionic chemical compound with the formula BaCl2. The substance has the CAS register number 10361-37-2 and EINECS number 233-788-1. It is stable, but incompatible with other materials like bromine trifluoride and furan-2-peroxycarboxylic acid. Barium chloride anhydrous is a white solid. Any of a variety of substances that contain barium. Most are whitish colored crystalline solids. They tend to be soluble in water and denser than water. They may be toxic by inhalation or possibly skin absorption.Barium chloride anhydrous is non-combustible. The substance itself does not burn but may decompose upon heating to produce corrosive and toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. In additionm, when heated, its container may explode.

Properties of Barium chloride:
Barium chloride anhydrous may react violently with BrF3 and 2-furan percarboxylic acid in its anhydrous form. Barium chloride can react with sulfate ion to generate a thick white precipitate of barium sulfate. Moreover, it can react with oxalate to give barium oxalate. The reaction equations are as the follwing:
Ba2+(aq) + SO42-(aq) → BaSO4(s)
Ba2+(aq) + C2O42-(aq) → BaC2O4(s)

Preparation of Barium chloride:
Barium chloride anhydrous is produced by barium hydroxide or barium carbonate. And then Barium chloride anhydrous reactS with hydrochloric acid to give hydrated barium chloride. In industry, it is prepared via a two step process from barium sulfate at high temperature. Afterward, The second step requires fusion of the reactants. The Barium chloride can then be leached out from the mixture with water.
BaSO4 + 4 C → BaS + 4 CO
BaS + CaCl2 → BaCl2 + CaS
In addition, Barium chloride can also be prepared by heating Barium chloride dihydrate at 125 °C. The reaction equation is as following:
BaCl2.2 H2O → BaCl2 +2 H2O

Uses of Barium Barium chloride:
 Because it is a cheap and soluble salt of barium, Barium chloride anhydrous is widely used in the laboratory. In industry, Barium chloride anhydrous is mainly used in the purification of brine solution in caustic chlorine plants and also in the manufacture of heat treatment salts, case hardening of steel, in the manufacture of pigments and other barium salts. It is commonly used as a test for sulfate ion. Barium chloride anhydrous is also used in fireworks to give a bright green color.

Safety information of Barium chloride:
When you are using Barium chloride anhydrous, you should be very cautious about it. It is toxic if swallowed and harmful by inhalation. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

Descriptors computed from structure of Barium chloride anhydrous:
(1)Canonical SMILES: [Cl-].[Cl-].[Ba+2]
(2)InChI: InChI=1S/Ba.2ClH/h;2*1H/q+2;;/p-2
(3)InChIKey: WDIHJSXYQDMJHN-UHFFFAOYSA-L

The toxicity of Barium chloride:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo intravenous 40mg/kg (40mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
cat LDLo subcutaneous 18mg/kg (18mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
dog LD50 unreported 90mg/kg (90mg/kg)   New Zealand Veterinary Journal. Vol. 47, Pg. 150, 1999.
dog LDLo oral 90mg/kg (90mg/kg)   "Drug Dosages in Laboratory Animals - A Handbook," Rev. ed., Barnes, C.D., and L.G. Eltherington, Berkeley, Univ. of California Press, 1973Vol. -, Pg. 53, 1973.
dog LDLo subcutaneous 10mg/kg (10mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
domestic animals - goat/sheep LDLo parenteral 7mg/kg (7mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE

BEHAVIORAL: MUSCLE WEAKNESS
New Zealand Veterinary Journal. Vol. 47, Pg. 150, 1999.
frog LDLo subcutaneous 910mg/kg (910mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
guinea pig LD50 oral 76mg/kg (76mg/kg)   Food Research. Vol. 7, Pg. 313, 1942.
guinea pig LDLo subcutaneous 55mg/kg (55mg/kg)   "Drug Dosages in Laboratory Animals - A Handbook," Rev. ed., Barnes, C.D., and L.G. Eltherington, Berkeley, Univ. of California Press, 1973Vol. -, Pg. 53, 1973.
horse/donkey LD50 unreported 800mg/kg (800mg/kg)   New Zealand Veterinary Journal. Vol. 47, Pg. 150, 1999.
mammal (species unspecified) LD50 oral 398mg/kg (398mg/kg) AUTONOMIC NERVOUS SYSTEM: OTHER (DIRECT) PARASYMPATHOMIMETIC

BEHAVIORAL: MUSCLE WEAKNESS

GASTROINTESTINAL: NAUSEA OR VOMITING
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 28(6), Pg. 45, 1984.
mouse LD50 intraperitoneal 39mg/kg (39mg/kg)   Farmakologiya i Toksikologiya Vol. 10, Pg. 107, 1975.
mouse LD50 intravenous 12mg/kg (12mg/kg)   Toxicology and Applied Pharmacology. Vol. 22, Pg. 150, 1972.
mouse LD50 unreported 7mg/kg (7mg/kg)   New Zealand Veterinary Journal. Vol. 47, Pg. 150, 1999.
mouse LDLo oral 70mg/kg (70mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
mouse LDLo subcutaneous 10mg/kg (10mg/kg)   National Technical Information Service. Vol. AEC-TR-6710,
rabbit LD50 unreported 170mg/kg (170mg/kg)   New Zealand Veterinary Journal. Vol. 47, Pg. 150, 1999.
rabbit LDLo intravenous 15mg/kg (15mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LDLo oral 170mg/kg (170mg/kg)   "Drug Dosages in Laboratory Animals - A Handbook," Rev. ed., Barnes, C.D., and L.G. Eltherington, Berkeley, Univ. of California Press, 1973Vol. -, Pg. 53, 1973.
rabbit LDLo parenteral 20mg/kg (20mg/kg) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"

KIDNEY, URETER, AND BLADDER: URINE VOLUME INCREASED
Medicina del Lavoro. Industrial Medicine. Vol. 30, Pg. 44, 1939.
rabbit LDLo subcutaneous 40mg/kg (40mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LD50 oral 118mg/kg (118mg/kg)   Food Research. Vol. 7, Pg. 313, 1942.
rat LD50 subcutaneous 178mg/kg (178mg/kg)   "Drug Dosages in Laboratory Animals - A Handbook," Rev. ed., Barnes, C.D., and L.G. Eltherington, Berkeley, Univ. of California Press, 1973Vol. -, Pg. 53, 1973.
rat LD50 unreported 150mg/kg (150mg/kg)   New Zealand Veterinary Journal. Vol. 47, Pg. 150, 1999.
rat LDLo intravenous 20mg/kg (20mg/kg) BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Journal of Laboratory and Clinical Medicine. Vol. 15, Pg. 35, 1929.

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