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Benzaldehyde propylene glycol acetal

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Name

Benzaldehyde propylene glycol acetal

EINECS 219-906-4
CAS No. 2568-25-4 Density 1.059 g/cm3
PSA 18.46000 LogP 2.12050
Solubility N/A Melting Point N/A
Formula C10H12O2 Boiling Point 242.4 °C at 760 mmHg
Molecular Weight 164.204 Flash Point 101.7 °C
Transport Information N/A Appearance Clear colorless to yellowish oily liquid
Safety 26-36 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 2568-25-4 (Benzaldehyde propylene glycol acetal) Hazard Symbols IrritantXi
Synonyms

2-Phenyl-4-methyl-1,3-dioxolane;4-Methyl-2-phenyl-1,3-dioxolane;

Article Data 38

Benzaldehyde propylene glycol acetal Synthetic route

57-55-6

propylene glycol

100-52-7

benzaldehyde

2568-25-4

4-methyl-2-phenyl-1,3-dioxolane

Conditions
ConditionsYield
With cyclohexane at 105℃; for 1h; Dean-Stark;99.7%
With phosphorus modified SO4(2-)/TiO2 In cyclohexane for 2h; Dean-Stark; Reflux;98%
With poly(styren-co-3-(1-vinyllimidazolium-3-yl)propane-1-sulfonate)-acid at 110℃; for 1.5h; Reagent/catalyst;96.2%
28224-73-9

1,3:4,6-di-O-benzylidene-D-mannitol

A

2568-25-4

4-methyl-2-phenyl-1,3-dioxolane

B

69-65-8

mannitol

Conditions
ConditionsYield
With propylene glycol; toluene-4-sulfonic acid In dichloromethane for 1h;A n/a
B 99%
100-52-7

benzaldehyde

122-51-0

orthoformic acid triethyl ester

2568-25-4

4-methyl-2-phenyl-1,3-dioxolane

Conditions
ConditionsYield
With tetra-N-butylammonium tribromide In propylene glycol at 20℃; for 12h; Inert atmosphere;9%
57-55-6

propylene glycol

1125-88-8

benzaldehyde dimethyl acetal

2568-25-4

4-methyl-2-phenyl-1,3-dioxolane

Conditions
ConditionsYield
With 5-sulfosalicylic Acid
100-52-7

benzaldehyde

2568-25-4

4-methyl-2-phenyl-1,3-dioxolane

Conditions
ConditionsYield
With tin(IV) chloride Anschliessend Behandeln mit (+/-)-1,2-Epoxy-propan.;
100-52-7

benzaldehyde

75-56-9, 16033-71-9

methyloxirane

2568-25-4

4-methyl-2-phenyl-1,3-dioxolane

Conditions
ConditionsYield
With N-(4-methyoxybenzyl)-2-cyanopyridinium hexafluoroantimonate for 0.5h; Ambient temperature;100 % Spectr.
57-55-6

propylene glycol

103-67-3

benzyl-methyl-amine

2568-25-4

4-methyl-2-phenyl-1,3-dioxolane

Conditions
ConditionsYield
With iodine In acetonitrile for 6h; Heating;14 % Spectr.
57-55-6

propylene glycol

100-51-6

benzyl alcohol

A

2568-25-4

4-methyl-2-phenyl-1,3-dioxolane

B

100-52-7

benzaldehyde

Conditions
ConditionsYield
With oxygen; palladium diacetate In neat (no solvent) at 150℃; under 3000.3 Torr; Catalytic behavior; Solvent;
2568-25-4

4-methyl-2-phenyl-1,3-dioxolane

105-34-0

methyl 2-cyanoacetate

3695-84-9, 14533-85-8, 14533-86-9

methyl benzylidenecyanoacetate

Conditions
ConditionsYield
With sulfuric acid; ethylenediamine at 80℃; for 12h;85.5%
120-72-9

indole

2568-25-4

4-methyl-2-phenyl-1,3-dioxolane

35173-74-1

3,3'-bis-indolyl(phenyl)methane

Conditions
ConditionsYield
With molecular iodine-loaded Cu4I4-MOF In neat (no solvent) at 20℃; for 10h; Friedel-Crafts Alkylation;85%

Benzaldehyde propylene glycol acetal Chemical Properties

IUPAC Name: 1,3-Dioxolane, 4-methyl-2-phenyl-
The MF of 1,3-Dioxolane, 4-methyl-2-phenyl- (2568-25-4) is C10H12O2.

                                
The MW of 1,3-Dioxolane, 4-methyl-2-phenyl- (2568-25-4) is 164.2.
Synonyms of 1,3-Dioxolane, 4-methyl-2-phenyl- (2568-25-4): 4-Methyl-2-phenyl-1,3-dioxolane ; 4-Methyl-2-phenyl-m-dioxolane ; Benzaldehyde propylene glycol acetal
Product Categories: Dioxanes & Dioxolanes;Dioxolanes;aldehyde Flavor 
Form: Clear colorless to yellowish oily liquid
Index of Refraction: 1.508 
EINECS: 219-906-4
Density: 1.059 g/ml 
Flash Point: 101.7 °C
Boiling Point: 242.4 °C
FEMA: 2130

Benzaldehyde propylene glycol acetal Uses

   1,3-Dioxolane, 4-methyl-2-phenyl- (2568-25-4) is used as a temporary food permit the use of spices.

Benzaldehyde propylene glycol acetal Toxicity Data With Reference

1.    

orl-rat LD50:3 g/kg

    FCTOD7    Food and Chemical Toxicology. 30 (1992),9S.
2.    

skn-rbt LD50:>5 g/kg

    FCTOD7    Food and Chemical Toxicology. 30 (1992),9S.

Benzaldehyde propylene glycol acetal Consensus Reports

Reported in EPA TSCA Inventory.

Benzaldehyde propylene glycol acetal Safety Profile

Moderately toxic by ingestion. Low toxicity by skin contact. When heated to decomposition it emits acrid smoke and irritating vapors.
Safety information of 1,3-Dioxolane, 4-methyl-2-phenyl- (2568-25-4):
Hazard Codes  Xi
Risk Statements 
36/37/38  Irritating to eyes, respiratory system and skin
Safety Statements 
26  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36  Wear suitable protective clothing
WGK Germany  2
RTECS  JI3870000

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