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Bis(triethyltin) sulfate
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Name

Bis(triethyltin) sulfate

 EINECS N/A
CAS No. 57-52-3 Density g/cm3
PSA 60.98000 LogP 5.35560
Solubility N/A Melting Point >300°C
Formula C12H30 O4 S Sn2 Boiling Point °Cat760mmHg
Molecular Weight 507.854 Flash Point °C
Transport Information N/A Appearance yellow amorphous powder
Safety Poison by ingestion, intraperitoneal, subcutaneous, intravenous, and parenteral routes. See also TIN COMPOUNDS and SULFATES. When heated to decomposition it emits toxic fumes of SOx.

Analytical Methods:

   

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.

Risk Codes R36/37/38
Molecular Structure Molecular Structure of 57-52-3 (BIS(TRIETHYLTIN)SULFATE) Hazard Symbols A poison by ingestion. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
Synonyms

4,6-Dioxa-5-thia-3,7-distannanonane,3,3,7,7-tetraethyl-, 5,5-dioxide (9CI); Bis(triethyltin) sulfate (6CI); Stannane,triethylhydroxy-, sulfate (2:1) (8CI); Tin, sulfatobis[triethyl- (7CI);Triethylhydroxytin sulfate; Triethyltin sulfate

 

Bis(triethyltin) sulfate Chemical Properties

IUPAC Name: bis(Triethylstannyl) sulfate
Synonyms of Bis(triethyltin) sulfate (CAS NO.57-52-3): Triaethylzinnsulfat ; Triethylhydroxystannane sulfate (2:1) ; Triethylhydroxytin sulfate ; Triethylstannium hydrogen sulfate ; Triethyltin sulfate ; Triethyltin sulphate ; 3,3,7,7-Tetraethyl-4,6-dioxa-5-thia-3,7-distannanonane 5,5-dioxide ; 4,6-Dioxa-5-thia-3,7-distannanonane, 3,3,7,7-tetraethyl-, 5,5-dioxide ; 4,6-Dioxa-5-thia-3,7-distannanonane, 3,3,7,7-tetraethyl-, 5,5-dioxide (9CI) ; Stannane, triethylhydroxy-, sulfate (2:1) (8CI) ; Tin, triethyl-, sulphate
InChI: InChI=1/6C2H5.H2O4S.2Sn/c6*1-2;1-5(2,3)4;;/h6*1H2,2H3;(H2,1,2,3,4);;/q;;;;;;;2*+1/p-2/rC12H30O4SSn2/c1-7-18(8-2,9-3)15-17(13,14)16-19(10-4,11-5)12-6/h7-12H2,1-6H3
InChIKey: BTVURVLQSDTSSS-QRAKGRNXAT
Std. InChI: InChI=1S/6C2H5.H2O4S.2Sn/c6*1-2;1-5(2,3)4;;/h6*1H2,2H3;(H2,1,2,3,4);;/q;;;;;;;2*+1/p-2
Std. InChIKey: BTVURVLQSDTSSS-UHFFFAOYSA-L
CAS NO: 57-52-3
Molecular Formula: C12H30O4SSn2
Molecular Weight: 507.8492
Molecular Structure :
EINECS: 200-335-4
H bond acceptors: 4
H bond donors: 0
Freely Rotating Bonds: 10
Polar Surface Area: 60.98 Å2
Flash Point: 182 °C
Enthalpy of Vaporization: 60.06 kJ/mol
Boiling Point: 377.3 °C at 760 mmHg
Vapour Pressure: 1.48E-05 mmHg at 25°C
Melting Point: >300°C

Bis(triethyltin) sulfate Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
bird - domestic LDLo intravenous 3mg/kg (3mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS		 British Journal of Pharmacology and Chemotherapy. Vol. 10, Pg. 16, 1955.
guinea pig LD50 intraperitoneal 3mg/kg (3mg/kg) PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE)

BEHAVIORAL: MUSCLE WEAKNESS		 British Journal of Industrial Medicine. Vol. 23, Pg. 222, 1966.
guinea pig LDLo oral 5mg/kg (5mg/kg)   British Journal of Pharmacology and Chemotherapy. Vol. 10, Pg. 16, 1955.
rabbit LDLo intraperitoneal 10mg/kg (10mg/kg)   British Journal of Pharmacology and Chemotherapy. Vol. 10, Pg. 16, 1955.
rabbit LDLo intravenous 3mg/kg (3mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

VASCULAR: REGIONAL OR GENERAL ARTERIOLAR OR VENOUS DILATION

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION		 British Journal of Pharmacology and Chemotherapy. Vol. 10, Pg. 16, 1955.
rabbit LDLo oral 10mg/kg (10mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

VASCULAR: REGIONAL OR GENERAL ARTERIOLAR OR VENOUS DILATION

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION		 British Journal of Pharmacology and Chemotherapy. Vol. 10, Pg. 16, 1955.
rat LD50 intraperitoneal 5700ug/kg (5.7mg/kg) BEHAVIORAL: MUSCLE WEAKNESS

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION

VASCULAR: REGIONAL OR GENERAL ARTERIOLAR OR VENOUS DILATION		 British Journal of Pharmacology and Chemotherapy. Vol. 10, Pg. 16, 1955.
rat LD50 intravenous 9050ug/kg (9.05mg/kg)   Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 242, Pg. 370, 1961.
rat LD50 parenteral 6mg/kg (6mg/kg) BRAIN AND COVERINGS: MENINGEAL CHANGES

BEHAVIORAL: MUSCLE WEAKNESS

BEHAVIORAL: COMA		 Biochemical Journal. Vol. 61, Pg. 406, 1955.
rat LDLo oral 10mg/kg (10mg/kg) BEHAVIORAL: MUSCLE WEAKNESS

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION

VASCULAR: REGIONAL OR GENERAL ARTERIOLAR OR VENOUS DILATION		 British Journal of Pharmacology and Chemotherapy. Vol. 10, Pg. 16, 1955.
rat LDLo subcutaneous 25mg/kg (25mg/kg) BEHAVIORAL: MUSCLE WEAKNESS

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION

VASCULAR: REGIONAL OR GENERAL ARTERIOLAR OR VENOUS DILATION		 British Journal of Pharmacology and Chemotherapy. Vol. 10, Pg. 16, 1955.

Bis(triethyltin) sulfate Safety Profile

RIDADR: UN3146
HazardClass: 6.1
PackingGroup: III
Poison by ingestion, intraperitoneal, subcutaneous, intravenous, and parenteral routes. See also TIN COMPOUNDS and SULFATES. When Bis(triethyltin) sulfate (CAS NO.57-52-3) is heated to decomposition, it emits toxic fumes of SOx.

Bis(triethyltin) sulfate Standards and Recommendations

OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3

Bis(triethyltin) sulfate Analytical Methods

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.

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