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Boron triiodide

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Name

Boron triiodide

EINECS 236-857-4
CAS No. 13517-10-7 Density 3.66g/cm3
PSA 0.00000 LogP 2.27630
Solubility Reacts with water. Melting Point 43-44°C
Formula BI3 Boiling Point 210°C
Molecular Weight 391.524 Flash Point °C
Transport Information N/A Appearance N/A
Safety A poison. Reacts violently with water. Incandescent reaction with red or white phosphorus. Exothermic reaction with ammonia. Incompatible with ethers, carbohydrates, POCl. When heated to decomposition it emits toxic fumes of I. See also BORON COMPOUNDS and IODIDES. Risk Codes 34
Molecular Structure Molecular Structure of 13517-10-7 (BORON TRIIODIDE) Hazard Symbols
Synonyms

Boroniodide (6CI);Boron iodide (BI3) (8CI);Boron triiodide;Triiodoborane;Triiodoboron;

Article Data 59

Boron triiodide Synthetic route

98370-06-0

1,1-bis(diiodoboryl)methane

A

1,3,5-triiodo-1,3,5-triboracyclohexane

B

(I2BCH2)2BI

C

13517-10-7

boron triiodide

Conditions
ConditionsYield
In neat (no solvent) B compd. degassed and heated under stirring at 160°C in vac. for 13 d; distd. in vac.;A 7%
B n/a
C n/a

boron trioxide

7681-82-5

sodium iodide

13517-10-7

boron triiodide

Conditions
ConditionsYield
800-1000°C;
7553-56-2

iodine

19287-45-7

diborane

13517-10-7

boron triiodide

7440-69-9

bismuth

7553-56-2

iodine

13517-10-7

boron triiodide

Conditions
ConditionsYield
In neat (no solvent) melting I2 with Bi;;

silver(I) iodide

13517-10-7

boron triiodide

Conditions
ConditionsYield
With B In neat (no solvent) in high vac. and at 1000°C; (thermal decompn. of AgI);
With B In neat (no solvent) in high vac. and at 1000°C; (thermal decompn. of AgI);

ferrobor

silver(I) iodide

13517-10-7

boron triiodide

Conditions
ConditionsYield
at ca 850°C in vac.;

boron

13517-10-7

boron triiodide

Conditions
ConditionsYield
With iodine reaction of B prepared according to Woehler, Saint-Claire Deville, at 700-800°C;
With hydrogen iodide at >1300°C with HI gas;
With silver(I) iodide at higher temp.;0%
With AgI at higher temp.;0%
With hydrogen iodide at >1300°C with HI gas;

boron

10034-85-2

hydrogen iodide

A

7553-56-2

iodine

B

13517-10-7

boron triiodide

Conditions
ConditionsYield
In neat (no solvent) well dried HI reacts at 700-800°C; Iron- and sodium borides present as impurities in amorphous boron have catalytic effect on formation of BI3;;
10034-85-2

hydrogen iodide

10294-34-5

boron trichloride

13517-10-7

boron triiodide

Conditions
ConditionsYield
well dried HI passed over BCl3 in porcelaine tube heated to red heat;;
at red heat in a china tube;
at red heat in a china tube;
well dried HI passed over BCl3 in porcelaine tube heated to red heat;;
10294-33-4

boron tribromide

A

13517-10-7

boron triiodide

B

BBr2I

C

BBrI2

Conditions
ConditionsYield
With hydrogen iodide byproducts: I2; 300-400 °C, in a heated tube;
With HI byproducts: I2; 300-400 °C, in a heated tube;

Boron triiodide Chemical Properties

Chemical Name: Boron triiodide
IUPAC NAME: Triiodoborane
CAS No.: 13517-10-7
EINECS: 236-857-4
Molecular Formula: BI3
Molecular Weight: 391.52 g/mol
Melting Point: 43-44°C
Density: 3.66 g/cm3
Boiling Point: 210 °C at 760 mmHg
Sensitive: Moisture Sensitive
Following is the structure of Boron triiodide (CAS No.13517-10-7):


Product Categories about Boron triiodide (CAS No.13517-10-7) are C-X Bond Formation (Halogen) ; Iodination ; Synthetic Reagents
The chemical synonymous of Boron triiodide (CAS No.13517-10-7) are Boron Iodide ; Boron Triiodide ; Bi ; Bi3 ; Borane, Triiodo- ; Borane,Triiodo- ; Triiodo-Boran ; Triiodoborane

Boron triiodide Safety Profile

A poison. Reacts violently with water. Incandescent reaction with red or white phosphorus. Exothermic reaction with ammonia. Incompatible with ethers, carbohydrates, POCl. When heated to decomposition it emits toxic fumes of I. See also BORON COMPOUNDS and IODIDES.
Hazard Codes: CorrosiveC
Risk Statements about Boron triiodide (CAS No.13517-10-7):
R34:Causes burns.
Safety Statements about Boron triiodide (CAS No.13517-10-7):
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.) 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.

Boron triiodide Specification

 Boron triiodide (CAS No.13517-10-7) is a chemical compound of boron and iodine with chemical formula BI3. It has a trigonal planar molecular geometry. It is a crystalline solid. Its dielectric constant is 5.38 and its heat of vaporization is 40.5 kJ/mol.

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