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Butyraldoxime

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Butyraldoxime

EINECS 203-792-8
CAS No. 110-69-0 Density 0.894 g/cm3
PSA 32.59000 LogP 1.24650
Solubility <0.1 g/100 mL at 20 °C in water Melting Point -29.5°C
Formula C4H9NO Boiling Point 148.968 °C at 760 mmHg
Molecular Weight 87.1216 Flash Point 64.514 °C
Transport Information N/A Appearance colourless liquid
Safety 45-36-23 Risk Codes 36-24-22
Molecular Structure Molecular Structure of 110-69-0 (Butyraldehyde oxime) Hazard Symbols ToxicT
Synonyms

Butylaldoxime;Butyraldoxime;NSC 1487;n-Butylaldoxime;n-Butyraldoxime;Butyraldehyde,oxime (6CI,7CI,8CI);Butanaldoxime;

Article Data 34

Butyraldoxime Chemical Properties

Chemistry informtion about N-Butyraldehyde Oxime (CAS NO.110-69-0) is:
IUPAC Name: (NE)-N-butylidenehydroxylamine
Synonyms: Tert-Nitrooctane ; Nitrous Acid N-Pentyl Ester ; N-Pentyl Nitrite ; Pentyl Nitrite ; N-Amyl Nitrite ; Nitramyl ; Nitrous Acid, Pentyl Ester ; Nitrousacid,Pentylester
Product Categories: Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes ; Organics
MF: C4H9NO
MW: 87.12
EINECS: 203-792-8 
Density: 0.89 g/cm3
Melting Point: -29.5°C
Flash Point: 64.5 °C
Boiling Point: 149 °C at 760 mmHg
Vapour Pressure: 2.26 mmHg at 25°C
Enthalpy of Vaporization: 42.57 kJ/mol
Storage temp.:  1.4367
Water Solubility: <0.1 g/100 mL at 20 ºC
BRN: 1698799
Stability: Stable. Combustible. Incompatible with strong oxidizing agents, powdered metals, acids. 
Following is the molecular structure of N-Butyraldehyde Oxime (CAS NO.110-69-0) is:

Butyraldoxime Uses

N-Butyraldehyde Oxime (CAS NO.110-69-0) can be used to make plastics and rubber.

Butyraldoxime Toxicity Data With Reference

1.    

msc-mus:lyms 1700 mg/L

    MUREAV    Mutation Research. 204 (1988),149.
2.    

ipr-mus LD50:200 mg/kg

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD277-689 .

Butyraldoxime Consensus Reports

Reported in EPA TSCA Inventory.

Butyraldoxime Safety Profile

A poison by intraperitoneal route. Mutation data reported. Flammable liquid when exposed to heat or flame. To fight fire, use alcohol foam, dry chemical. Highly explosive. Can explode during vacuum distillation. Incompatible with oxidizing materials, metallic impurities. When heated to decomposition it emits toxic fumes of NOx. See also ALDEHYDES.
Hazard Codes:
ToxicT
Risk Statements:
R36:Irritating to eyes. 
R24:Toxic in contact with skin. 
R22:Harmful if swallowed.
Safety Statements:
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S36:Wear suitable protective clothing. 
S23:Do not breathe vapour.
RIDADR: 2840
RTECS: ES3500000
HazardClass: 3
PackingGroup: III

Butyraldoxime Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid

Butyraldoxime Specification

 N-Butyraldehyde Oxime (CAS NO.110-69-0) is a colourless liquid. It is slightly less dense than water and vapors heavier than air. It is highly explosive during vacuum distillation.And it is incompatible with oxidizing materials. It is also incompatible with metallic impurities. It may react with strong acids. 
It may cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. It will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

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