Gold-catalyzed highly enantioselective synthesis of axially chiral allenes
Axially chiral allenes are synthesized from chiral propargylamines catalyzed by KAuCl4 in high yields (up to 93% yield) and excellent enantioselectivities (up to 97% ee) in CH3CN at 40 °C. The reaction has been applied to the synthes
Lo, Vanessa Kar-Yan,Wong, Man-Kin,Che, Chi-Ming
p. 517 - 519
(2008/09/19)
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