A Rh-catalyst derived from (NacNac)Rh(COE)(N2) effects the hydrogenation and silylation of P-P bonds to give secondary phosphines and silylphosphines, (Ph2PH) and (Ph2PSiRR′2) respectively; the latter process is shown to also involve the silylation of secondary phosphines. The Royal Society of Chemistry.
Geier, Stephen J.,Stephan, Douglas W.
p. 99 - 101
(2008/09/20)
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