- donor-acceptor oligogermanes: Synthesis, structure, and electronic properties
-
A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these donor-acceptor oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.
- Zaitsev, Kirill V.,Kapranov, Andrey A.,Churakov, Andrei V.,Poleshchuk, Oleg Kh.,Oprunenko, Yuri F.,Tarasevich, Boris N.,Zaitseva, Galina S.,Karlov, Sergey S.
-
-
Read Online
- INTERACTION OF PENTAFLUOROPHENYL HYDRIDES OF GERMANIUM WITH TRIETHYLTHALLIUM
-
(C6F5)3GeTlEt2 and 2TlEt have been prepared by reaction of tris(pentafluorophenyl)germane with triethylthallium.The reaction of the dihydride (C6F5)2GeH2 with triethylthallium gives an unusual product of composition n.The possibl
- Bochkarev, M.N.,Basalgina, T.A.,Kalinina, G.S.,Razuvaev, G. A.
-
p. 405 - 410
(2007/10/02)
-