Reactions of Trialkylsilyl Trifluoromethanesulfonates, IV. - 1,3-Trialkylsiloxy Shift - a New Rearrangement Reaction During the Silylation of Nitroalkanes
Nitroalkanes 1 with C-H bonds in β-position react with two-fold molar amounts of trialkylsilyl triflates 2 in the presence of triethylamine to yield 2-(trialkylsiloxy)oxime O-trialkylsilyl ethers 5 by 1,3-trialkylsiloxy shift.Oxime ethers 5 are also obtai
Feger, Harry,Simchen, Gerhard
p. 428 - 437
(2007/10/02)
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