Air-stable secondary phosphine oxide or chloride (Pre)ligands for cross-couplings of unactivated alkyl chlorides
In situ generated and crystallographically well-defined, isolated palladium complexes derived from seven novel air-stable secondary phosphine oxides or chlorides enabled challenging Kumada-Corriu cross-couplings of unactivated alkyl chlorides bearing β-hy
Ackermann, Lutz,Kapdi, Anant R.,Schulzke, Carola
supporting information; experimental part
p. 2298 - 2301
(2010/08/05)
Reductive Deoxygenation of Aryl Aldehydes and Ketones and Benzylic, Allylic, and Tertiary Alcohols by ZnI2-NaCNBH3
Sodium cyanoborohydride in the presence of zinc iodide is found to exhibit unique and selective reducing properties.The reagents reduce aryl aldehydes and ketones as well as benzylic, allylic, and tertiary alcohols to the corresponding hydrocarbons.
Lau, C. K.,Dufresne, Claude,Belanger, Patrice C.,Pietre, Sylvie,Scheigetz, John
p. 3038 - 3043
(2007/10/02)
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