One-step C=N, C=O bonds cleavage and C=O, C=N bonds formation over supported ionic liquid in water
At ambient reaction temperature, the silica gel confined ionic liquid catalysts were perfectly combined with water as an effective catalytic system for simultaneous C=N and C=O bonds transformation with a TONs exceeding 300 mol mol-1.
Synthesis of highly substituted pyrroles via nucleophilic catalysis
Figure presented. A nucleophilic catalysis method providing a concise synthesis of di-, tri-, and tetrasubstituted pyrroles is described. This regioselective one-pot method relies on nucleophilic catalysis of the intermolecular addition of oximes to activ
Ngwerume, Simbarashe,Camp, Jason E.
supporting information; experimental part
p. 6271 - 6274
(2010/11/19)
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