Pd(CH3CN)4(BF4)2-Assisted Attack of Nitriles on Olefins. A Pd Analogue of the Ritter Reaction
The strongly electrophilic complex Pd(CH3CN)4(BF4)2 (1) activates a variety of olefins to undergo nucleophilic attack by nitriles to give nitrilium salts.These nitrilium salts undergo reaction with a variety of nucleophiles including electron-rich aromatics, alcohols, and amines, ultimately producing a variety of heterocyclic ring systems.
Hegedus, Louis S.,Mulhern, Thomas A.,Asada, Hideki
p. 6224 - 6228
(2007/10/02)
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