Diastereoselective synthesis of carbapenams via Kinugasa reaction
(Chemical Equation Presented) A facile approach to carbapenams via Kinugasa reaction between terminal copper acetylides and nonracemic cyclic nitrones derived from malic and tartaric acid is reported. The stereochemical preferences observed in these reactions are explained. The reaction provides an entry to the carbapenams basic skeleton.
Stecko, Sebastian,Mames, Adam,Furman, Bartlomiej,Chmielewski, Marek
supporting information; experimental part
p. 7402 - 7404
(2009/05/07)
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