OZONOLYSIS OF ALKENES AND REACTIONS OF POLYFUNCTIONAL COMPOUNDS. XXVIII. SYNTHESIS OF RACEMIC HOMO- AND BISHOMODIHYDROCITRONELLALS
A five-stage synthesis was developed for racemic 4,8-dimethylnonanal and diastereomeric 4,8-dimethyldecanal (attractants of meal worms Tribolium castaneum, T. confusum) from dimethylcyclooctadiene.
Odinokov, V. N.,Akhmetova, V. R.,Cheskis, B. A.,Moiseenkov, A. M.,Tolstikov, G. A.
p. 246 - 247
(2007/10/02)
Synthesis of 4(RS),8(S)-Dimethyldecanal: An Aggrigation Pheromone of Red Flour Beetles
A simple and straight forward synthesis of the pheromone 4(RS),8(S)-dimethyldecanal (IX) has been described starting from 7-hydroxycitronellal (I).
Randad, R. S.,Kulkarni, G. H.
p. 296 - 298
(2007/10/02)
DIASTEREOTOPIC GROUP SELECTIVITY AT A PROSTEREOGENIC CARBON CENTER: SYNTHESIS OF (+/-)-SYN-4,8-DIMETHYLDECANAL
A group selective dealkylation reaction of a bridged ketal with trimethylsilyl iodide serves to control stereochemistry at carbon centers that are separated by five atoms.In combination with the iron/copper promoted fragmentation reaction of a hydroperoxi
Schreiber, Stuart L.,Hulin, Bernard
p. 4561 - 4564
(2007/10/02)
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