Methyl Trideuteriomethyl (E)-(α-Bromoarylidene)malonates: Simple Stereochemical Probes in Nucleophilic Vinylic Substitution near the Retention/Stereoconvergence Borderline
Methyl trideuteriomethyl (E)-(α-bromo-p-methyl- and -p-nitrobenzylidene)malonates (4 and 5) were prepared.These electrophilic bromo olefins are activated to vinylic substitution by ywo chemically identical but isotopically distinguishable CO2Me groups.The
Rappoport, Zvi,Gazit, Aviv
p. 6698 - 6710
(2007/10/02)
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