- Smectic-smectic phase transitions in binary liquid-crystalline mixtures of DB5-T8
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We have used high-resolution x-ray diffraction and ac calorimetry to study the liquid-crystalline smectic-A-smectic-A phase transitions in binary mixtures of polar mesogenic compounds DB5 phenyl ester> and T8 ethenyl> phenyl ester>.A detailed synthesis for each of these compounds is presented.The smectic A1 phase in this system shows two collinear diffuse x-ray maxima at incommensurate wave vectors, indicating a tendency to form the predicted Ai1 phase with two strongly coupled density modulations having incommensurate wavelengths.The Ad peak position, while both temperature and concentration dependent, is remarkably constant along the N-Ad phase boundary.In the vicinity of 16 mol percent T8, both the x-ray and heat-capacity results are reproducibly history dependent.The simultaneous observation of sharp A2 and Ad peaks most likely results from phase coexistence, but a condensed incommensurate Ai2 phase cannot be ruled out.
- Fontes, Ernest,Lee, Wah Keat,Heiney, Paul A.,Nounesis, George,Garland, Carl W.,et al.
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p. 3917 - 3929
(2007/10/02)
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- Facile Synthesis of 4-alkylphenyl 4-(4-Nitrobenzoyloxy)Benzoate (DBXNO2) and its Cyano Analog (DBXCN)
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Two series of unsymmetrical phenylbenzoate analogs of thermotropic liquid crystals, namely, 4-alkylphenyl 4(4-nitrobenzoyloxy) benzoate (DBXNO2) and its cyano analog (DBXCN) are synthesized by a new route from benzyloxybenzoic acid.The first ester linkage of these phenylbenzoates is made by a condensation reaction between benzyloxybenzoic acid and an alkylphenol in the presence of carbodiimide and a base to give compound 6.A benzyl deprotection reaction of 6 is carried out by catalytical hydrogenation to yield compound 7.The second ester connection is performed by a condensation reaction between 7 and p-cyano or p-nitrobenzoyl chloride.This reaction sequence leads to the final products, DBXNO2 or DBXCN, in an overall yield of 50percent or 37percent, respectively.
- Chiang, Long Y.
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p. 137 - 142
(2007/10/02)
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