Cleavage of Carbon-Carbon Bonds with High Stereochemical Control. 6. Asymmetric Synthesis of Chiral C-Centered Organosilanes by Haller-Bauer Cleavage of Optically Active, Nonenolizable α-Silyl Phenyl Ketones
Sequential alkylation and methylation of l-menthyl ester 10 provides diastereomeric mixtures in which 12 is slighthly enhanced over 13.Conversely, C-silation and alkylation of propionate ester 11 delivers 13 in excess.In either cause, a single chromatogra
Gilday, John P.,Gallucci, Judith C.,Paquette, Leo A.
p. 1399 - 1408
(2007/10/02)
Optically Enriched Alkyltrimethylsilanes by Haller-Bauer Cleavage of Optically Active, Nonenolizable α-Silyl Phenyl Ketones
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Paquette, Leo A.,Gilday, John P.,Ra, Choon Sup,Hoppe, Manfred
p. 704 - 706
(2007/10/02)
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