Functionalized 3(2H)-furanones via photooxygenation of (β-keto)-2- substituted furans: Application to the biomimetic synthesis of merrekentrone C
Photooxygenation of (β-keto)-2-substituted furans leads, in a one pot operation, to functionalized 3(2H)-furanones with good to excellent yields. This methodology was applied as a key-step to the concise and biomimetic synthesis of the sesquiterpene merre
Gryparis, Charis,Lykakis, Ioannis N.,Efe, Christina,Zaravinos, Ioannis-Panayotis,Vidali, Theonymphi,Kladou, Eugenia,Stratakis, Manolis
p. 5655 - 5658
(2011/09/16)
A NEW APPROACH TO POLYFUNCTIONAL 3(2H)-FURANONES
A selective oxidative opening of the heterocyclic nucleus of 2-(acylmethyl)-5-methylfurans or 2-(5-methyl-2-furyl)-1,3-dicarbonyl compounds by m-chloroperbenzoic acid allows the one-pot synthesis of 3(2H)-furanone derivatives.The same methodology, extende
A selective oxidative fission of the heterocyclic nucleus of 5-methyl-2-(acylmethyl)furans or 2-(5-methyl-2-furyl)-1,3-dicarbonyl compounds by m-chloroperbenzoic acid allows the easy synthesis of the 3(2H)-furanone system.
Antonioletti, R.,Bonadies, F.,Scettri, A.
p. 2297 - 2298
(2007/10/02)
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