HL2[(1,2-O2C6H4)3] (L = DMSO or DMF): A convenient proton source with a weakly basic phosphorus(V) Anion
Treating phosphorus pentachloride with catechol (3 equiv) followed by the addition of dimethyl -sulfoxide (DMSO) or dimethylformamide (DMF) affords isolable Bronsted acids of the tris-(o-phenylenedioxy)phosphate anion, [P(1,2-O2C6Hs
Siu, Paul W.,Gates, Derek P.
p. 4491 - 4499
(2009/12/06)
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