Configuration-dependent ring opening of silyloxiranes: synthesis of functionalized alkenes or tetrahydrofurans
cis- and trans-Silyloxiranes with a potential tosylate or bromide leaving group in the β position are available by the diastereospecific reduction of the corresponding alkynes with DIBAL-H and hydrosilylation with silanes, respectively. In the reaction wi
Lange, Jens,Schaumann, Ernst
experimental part
p. 4674 - 4684
(2009/12/06)
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