Rhodium-catalyzed homocoupling of (1-Acyloxyvinyl)silanes: Synthesis of 1,3-diene-2,3-diyl diesters and their derivatives
1,3-Diene-2,3-diyl diesters are synthesized by rhodium-catalyzed homocoupling of (1-acyloxyvinyl)silanes. Double transmetalation between vinylsilane and rhodium intermediate in a single catalytic cycle is the key in this reaction. From the homocoupling pr
Yue, Yanni,Yamamoto, Hiroki,Yamane, Motoki
experimental part
p. 2831 - 2835
(2010/03/03)
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