Reaction of bis(alkynyl)silanes with tris(pentafluorophenyl)-borane: Synthesis of bulky silole derivatives by means of 1,1-carboboration under mild reaction conditions
The strong Lewis acid tris(pentafluorophe-nyl)borane [B(C6F 5)3] reacts rapidly with dimethyl-bis(phenylethynyl)silane (1c) at room temperature in toluene by shift of a pentafluorophenyl (C 6F5) group
Dierker, Gereon,Ugolotti, Juri,Kehr, Gerald,Froehlich, Roland,Erker, Gerhard
The use of very electrophilic boranes RB(C6F5) 2 widens the scope of the 1,1-carboboration reaction substantially. Simple terminal alkynes HCCR undergo this reaction with the RB(C 6F5)2 reagents rapidly under mild conditions to give high yields of very useful new alkenylborane products. Even internal alkynes RCCR undergo 1,1-carboboration with the RB(C6F 5)2 reagents to provide a novel way of carbon-carbon σ-bond activation. Variants of these reactions involving phosphorus substituted alkynes and more complex bisalkynyl main group and transition metal substrates give rise to the formation of very interesting functionalized metallacyclic products upon treatment with RB(C6F5) 2 reagents by means of reaction sequences involving selective 1,1-carboboration steps.
Kehr, Gerald,Erker, Gerhard
p. 1839 - 1850
(2012/03/12)
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