- Nouveaux complexes a enchainement Ge-Ru-Ge: les bis(dimethylgermyl)alcane ruthenium tetracarbonyles. I. Synthese et reactions de clivage
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Bis(dimethylgermyl)alkane ruthenium tetracarbonyls (n = 1, 2) are obtained by reaction of bis(dimethylgermyl)alkanes Me2(H)Ge(CH2)nGe(H)Me2 (n = 1, 2) with Ru3(CO)12 under UV irradiation, or by heating.Various CO substitution reactions with phosphines by heating and cleavage reactions with protonic, electrophilic, nucleophilic or radical reagents are described.X-O oxides (X = Hg, C5H5N, C6H5N, Me2S) are deoxidized by these complexes.
- Barrau, Jacques,Hamida, Najib Ben,Satge, Jacques
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- Reactivity of [bis(dimethylgermyl)alkane]iron tetracarbonyls with carbonyl compounds
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[Bis(dimethylgermyl)alkane]iron tetracarbonyls, Me2Ge(CH2)nGeMe2Fe(CO)4 (n = 1, 2), react with chloral, propionaldehyde, and benzaldehyde to give heterocyclic expansion reactions. Thermal decompositio
- Barrau, Jacques,Hamida, Najib Ben,Agrebi, Hamid,Satgé, Jacques
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p. 1674 - 1678
(2008/10/08)
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