SURFACE ENHANCED ENANTIODIFFERENTIATION IN REACTIONS OF CHIRAL ACETOACETATES
The stereoselectivity of the alkylation of chiral acetoacetates by racemic secondary alkyl halides changes when the reaction is carried out on a solid support; the change can be interpreted in terms of a model involving surface imposed conformational restrictions.
Bram, Georges,Cabaret, Daniel,Welvart, Zoltan,Geraghty, Niall W. A.,Garwey, James