- KINETICS AND MECHANISM OF THE MONOMOLECULAR HETEROLYSIS OF INDUSTRIAL ORGANOHALOGEN COMPOUNDS. XIII. NATURE OF SALT EFFECTS IN THE DEHYDROBROMINATION OF 7α-BROMOCHOLESTEROL BENZOATE IN γ-BUTYROLACTONE, NITROBENZENE, AND o-XYLENE
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By the verdazyl method we studied the influence of salts on the rate of heterolysis of 7α-bromocholesterol benzoate in γ-butyrolactone, nitrobenzene, and o-xylene, v = k.It was shown that the rate of the heterolysis of 7β-bromocholesterol benzoate in these solvents is higher than the rate of the heterolysis of the α epimer by factors of 7, 12, and 110 respectively.
- Ponomarev, N. E.,Dvorko, G. F.
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p. 388 - 400
(2007/10/02)
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