The chemical behavior of latrunculins A (1) and (B) (Lat A and B) under a variety of reaction conditions is described.The combination of the macrolide, the THP-lactol, and the 2-thiazolidinone rings was found to result on interesting unpredicted chemical transformations.The structures of two new Lats, 6,7-epoxy-Lat A (3) and Lat M (4) isolated from Latrunculia magnifica, are discussed.
Blasberger, Dina,Carmely, Shmuel,Cojocaru, Miriam,Spector, Ilan,Shochet, Nava R.,Kashman, Yoel
p. 1171 - 1188
(2007/10/02)
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