Pentafluorophenyl derivatives, methods of production thereof, and method of optical resolution of chiral carboxylic acids
Pentafluorophenyl derivatives are expressed by the formula (I): STR1 where X represents an alkyl group having from 1 to 4 carbon atoms or a halogen atom; Y represents any group of --CH2 OH, --COOH, --COCl, --CON1 R2, or --
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(2008/06/13)
Asymmetric synthesis of α-methyl carboxylic acid derivatives stereochemistry in acidic ring opening of epoxides
Optically active α-methyl carboxylic acid derivatives were prepared via reaction of microbially produced epoxides with trimethylaluminum. Stereochemistry of the ring opening reaction was discussed through an MO calculation.
Fukumasa,Furuhashi,Umezawa,Takahashi,Hirai
p. 1059 - 1062
(2007/10/02)
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