Accelerating water exchange for GDIII chelates by steric compression around the water binding site
The water exchange process was accelerated for nine-coordinate, monohydrated macrocyclic GdIII complexes by inducing steric compression around the water binding site; the increased steric crowding was achieved by replacing an ethylene bridge of
Ruloff, Robert,Toth, Eva,Scopelliti, Rosario,Tripier, Raphael,Handel, Henri,Merbach, Andre E.
Novel Bifunctional Macrocyclic Chelating Agents Appended with a Pendant-Type Carboxymethylamino Ligand and Nitrobenzyl Group and Stability of the (88)YIII Complexes