- METHOD FOR PRODUCING CARBOXYLIC ACID ESTER, ESTERIFICATION AGENT AND RING-OPENING ADDITION CATALYST
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PROBLEM TO BE SOLVED: To provide a method for producing a carboxylic acid ester using a catalyst compound which is easy to handle and has high activity and to provide an esterification agent and a ring-opening addition catalyst suitably used for the production method. SOLUTION: An imidazole compound having a specific structure is allowed to exist during a reaction when a carboxylic acid ester is produced by reacting (A) at least one electrophilic body selected from the group consisting of at least one hydroxy group-donating compound selected from the group consisting of a phenol compound and alcohol and an epoxy group-donating compound composed of an epoxy compound and (B) at least one nucleophilic body selected from the group consisting of carboxylic acid, a carboxylic acid halide, a carboxylic acid ester and a carboxylic acid anhydride. SELECTED DRAWING: None COPYRIGHT: (C)2017,JPO&INPIT
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Paragraph 0218
(2017/11/04)
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- METHOD FOR MANUFACTRURING BETA-(METH)ACRYLOYLOXY-GAMMA-BUTYROLACTONES
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The art relates to provision of a method for manufacturing an (meth)acrylic polymerizable monomer that can be used in various applications, such as an optical material, a resist material, a coating material and a laminate material, and provision of a new β-(meth)acryloyloxy-γ-butyrolactone compound by applying the manufacturing method. The method for manufacturing the β-(meth)acryloyloxy-γ-butyrolactone compound is described, in which a (meth)acrylate compound having a carbonyl group and a ketene compound are condensed and isomerized. Further, the manufacturing method is applied to the new β-(meth)acryloyloxy-γ-butyrolactone compound.
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Paragraph 0079
(2015/05/13)
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- PROCESS FOR PRODUCING LACTONE
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A method for producing lactones, which comprises reacting an amide compound of Formula (I): [wherein X represents a halogen atom; R, R' and R1 to R6 each independently represents a hydrogen atom or any desired substituent; and n represents an integer of 0 to 2] with an aqueous medium.
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- Process for producing monomer
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A process for producing a monomer for resists represented by the following general formula 1: wherein R1 represents hydrogen or an optionally substituted alkyl group; R2, R3 and R4 each independently represent hydrogen or a substituent; and X, Y and Z each independently represent a direct bond or an optionally substituted alkylene group with 1 to 3 chain members, the process comprising carrying out esterification or transesterification in the presence of a biocatalyst.
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- Chemical amplifying type positive resist composition
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A chemical amplifying type positive resist composition, excellent in balance of performance of resolution and sensitivity, having high dry etching resistance and comprising; a resin having a polymerization unit derived from a monomer represented by the following formula (I): wherein R1 and R2 independently represent hydrogen or an alkyl group having 1 to 4 carbons, and R3 represents hydrogen or a methyl group, the resin being insoluble in alkali itself but becoming alkali-soluble due to the action of an acid; and an acid generating agent is provided.
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- Process for preparing β-hydroxy-γ-butyrolactones and β-(meth)acryloyloxy-γ-butrolactones
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The present invention provides a process for preparing β-hydroxy-γ-butyrolactone or β-methyl-β-hydroxy-γ-butyrolactone represented by the formula (1): wherein R1is hydrogen or methyl, which entails a) cyanating glycidol or 2-methyl-2,3-epoxypropanol, b) hydrolyzing the product of step a), and c) lactonizing the product of step b).
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