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13190-97-1

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β,γ-dihydropolyprenyl alcohol derivatives and pharmaceutical composition containing a polyprenyl compound
A β,γ-dihydropolyprenyl alcohol derivative having the formula: STR1 wherein n is an integer of 5 to 7 and R is hydrogen, a lower alkyl group or an aliphatic or aromatic acyl group, is new and useful as a phylactic agent against human and animal infectious diseases. Other disclosed polyprenyl compounds are also useful as such agents.
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(2008/06/13)

Stereoselective Synthesis of Solanesol and all-trans-Decaprenol
Allylic p-tolyl sulphonates (5), (14), and (16) couple with allylic bromide (7) and geranyl bromide to produce regio- and stereo-chemically pure 1,5-diene systems.The coupling of all-trans-ω-bromogeranyl acetate (7) with geranyl p-tolyl sulphone (5) and higher isoprenologues (21), (24), and (27), followed by reductive elimination of p-tolylsulphonyl group, furnishes a stereoselective synthesis of all-trans-polyprenols (3), (23), (26), and decaprenol (1b).Solanesol (1a) was synthesised using trans-4-chloroprenyl acetate (29) instead of (7).
Sato, Kikumasa,Inoue, Seiichi,Onishi, Akira,Uchida, Nobuhiko,Minowa, Nobuto
p. 761 - 769
(2007/10/02)

Hypertension treating agent containing polyprenyl alcohol
This invention relates to a hypertension treating agent comprising a polyprenyl alcohol or an ester thereof of the general formula: STR1 wherein n represents an integer of 7-10 and A represents a group of the general formula: STR2 in which a and b each represent hydrogen or they may form a bond, or STR3 in which R represents hydrogen or --COR', R' being a saturated or unsaturated aliphatic hydrocarbon group of 1-17 carbon atoms; cyclohexyl group; unsubstituted phenyl group or phenyl group substituted with a halogen atom or a lower alkoxy group; (halogen atom-substituted phenoxy)-lower alkyl group; or pyridyl group.
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(2008/06/13)

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Chemical Properties

Appearance/Colour :brown waxy solid
Melting Point: 33 °C
Boiling Point: 685.6 °C at 760 mmHg
Flash Point:130.2 °C
Density: 0.889 g/cm³
Solubility:Chloroform (Slightly), Ethyl Acetate (Slightly)
Storage Temp.:−20°C
Vapor Pressure: 9.21E-22mmHg at 25°C
Refractive Index: 1.506
PKA: 14.42±0.10(Predicted)
Merck: 14,8703
PSA: 20.23000
LogP: 14.75690

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