A New Entry to Difluoromethylene Compounds; An Electrochemical Method
Electroreduction of dibromodifluoromethane in the presence of diphenyldiselenide and olefins in a DMF-(Pt)-(Al) system provided adducts of in situ generated bromodifluoromethyl radical and phenylselenenyl group to olefins.One electron transfer from benzen
Perfluoroalkyl-selenation of olefins has been performed by the reaction of diphenyl diselenide with sodium borohydride followed with perfluoroalkyl halides (RfX) and olefins where one electron transfer from phenylseleno anion to RfX occurs, generating per
Uneyama, Kenji,Kitagawa, Kouichi
p. 375 - 378
(2007/10/02)
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