Practical radical cyclizations with arylboronic acids and trifluoroborates
Practical radical cyclizations using organoboronic acids and trifluoroborates take place in water, open to air, and in a scalable fashion employing catalytic silver nitrate and stoichiometric potassium persulfate. Both Pschorr-type cyclizations and tandem radical cyclization/trap cascades are described, illustrating the utility of these mild conditions for the generation of polycyclic scaffolds.
Lockner, Jonathan W.,Dixon, Darryl D.,Risgaard, Rune,Baran, Phil S.
p. 5628 - 5631
(2011/12/03)
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