Fe(VI) catalyzed manganese redox chemistry: Permanganate and super-iron alkaline batteries
In principle, alkali permanganates represent a substantial cathodic charge source for electrochemical storage, but high rate charge transfer has been inefficient. This study presents a novel Fe(VI) species (super-iron) and manganese redox chemistry synerg
Licht, Stuart,Ghosh, Susanta,Naschitz, Vera,Halperin, Nadezhda,Halperin, Leonid
On the knowledge of oxides A[MO4]: On LiMnO4, KMnO4, RbMnO4, CsMnO4 as well as RbIO4, CsIO4. (-What does the crystal structure of . . . mean? -)
These investigations confirm again that, sufficient purity, symmetry and lack of disorder etc. of investigated single crystals provided: the structure of a solid is characterized only if a) lattice constants are determined precisely by powder data; b) a couple of single crystals is sufficiently investigated by film data; c) the quantitative comparison of crystal structures of a chemical series like A[MnO4] with another one like A2[SO4] alone enables one to estimate the quality of different structural investigations of the same material. d) The crystal structure of a solid is still non-existent.
Hoppe,Fischer,Schneider
p. 1135 - 1142
(2008/10/08)
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