Photo-driven anti-Markovnikov alkyne hydration in self-assembled hollow complexes
Under UV-light irradiation, the anti-Markovnikov hydration of internal arylalkynes proceeds in the cavity of an electron-deficient coordination cage to give benzyl ketones; the reaction is triggered by cage-mediated, photo-induced electron transfer from the alkynes to the cage.
Murase, Takashi,Takezawa, Hiroki,Fujita, Makoto
supporting information; experimental part
p. 10960 - 10962
(2011/11/13)
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