Chiral bicyclic [2.2.2] octadiene ligands for Rh-catalysed catalytic asymmetric conjugate additions to acyclic enones: A quantitative structure-property relationship
A series of chiral bicyclic [2.2.2]diene ligands gave variable ee values for Rh-catalysed asymmetric conjugate addition to an acyclic enone. The interplay between electronic and steric effects was captured in a robust predictive quantitative structure-property relationship (QSPR) model for enantioselectivity. The Royal Society of Chemistry 2012.
Luo, Yunfei,Berry, Neil G.,Carnell, Andrew J.
p. 3279 - 3281
(2012/04/23)
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