Diastereoselective solid-phase radical addition to oxime ether anchored to polymer support
Stereocontrol in radical reactions of oxime ether anchored to polymer support was studied. Highly diastereoselective solid-phase radical reaction was achieved by using triethylborane and diethylzinc as a radical initiator at low reaction temperature, providing a novel method for the synthesis of the α-amino acid derivatives with excellent diastereoselectivities.
Miyabe, Hideto,Konishi, Chihiro,Naito, Takeaki
p. 540 - 544
(2007/10/03)
Stereocontrol in solid-phase radical reactions: Radical addition to oxime ether anchored to polymer support
(Matrix presented) A high degree of stereocontrol in solid-phase radical reactions was achieved by using triethylborane and diethylzinc as a radical initiator at low reaction temperature. Alkyl radical addition to Oppolzer's camphorsultam derivatives of o
Miyabe, Hideto,Konishi, Chihiro,Naito, Takeaki
p. 1443 - 1445
(2007/10/03)
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