cas 13928-68-2, 5,7-DIMETHYLADAMANTANE-1,3-DICARBOXYLIC ACID | Articles data ｜lookchem

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13928-68-2

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Adamantane-containing esters as potential components of thermostable lubricating oils
Some esters of dimethyladamantanedicarboxylic acids with aliphatic alcohols and the ester of dimethyladamantanedicarbinol with an aliphatic acid have been synthesized, and their properties have been studied; their viscosity-temperature properties and ther
Bagrii,Maravin
(2013)
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The first selective one-pot synthesis of 1,3-dicarbonyl adamantanes from adamantane and 1,3-dimethyladamantane
A new approach to a simple one-pot functionalization of adamantane and 1,3-dimethyladamantane with CO and various nucleophiles in the presence of the superelectrophilic complex, CBr4·2AlBr3 provides access to important 1,3-dicarbonyl adamantanes with two new functional groups at the bridge-head positions.
Akhrem, Irena S.,Avetisyan, Dzhul'Etta V.,Afanas'Eva, Luidmila V.
supporting information; experimental part
p. 3493 - 3496
(2012/08/27)

The first one-pot synthesis of 1,3-dicarbonyl adamantanes from 1-bromoadamantanes
Treatment of 1-bromoadamantane and 1-bromo-3,5-dimethyladamantane with CBr4·2AlBr3 under carbon monoxide atmosphere followed by quenching with nucleophiles affords 1,3-dicarbonyl adamantanes.
Akhrem, Irena S.,Avetisyan, Dzhul'Etta V.,Afanas'Eva, Lyudmila V.,Goryunov, Evgenii I.,Churilova, Irina M.,Petrovskii, Pavel V.,Kagramanov, Nikolai D.
experimental part
p. 259 - 261
(2012/07/14)

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10347-01-0
1,3-dihydroxy-5,7-dimethyladamantane

Chemical Properties

Melting Point: 273-274℃ (acetic acid )
Boiling Point: 371.4°C at 760 mmHg
Flash Point:192.6°C
Density: 1.379±0.06 g/cm3 (20 ºC 760 Torr)
Vapor Pressure: 1.55E-06mmHg at 25°C
PSA: 74.60000
LogP: 2.52240

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