Trineopentylphosphine: A conformationally flexible ligand for the coupling of sterically demanding substrates in the Buchwald-Hartwig amination and suzuki-miyaura reaction
Trineopentylphosphine (TNpP) in combination with palladium provides a highly effective catalyst for the Buchwald-Hartwig coupling of sterically demanding aryl bromides and chlorides with sterically hindered aniline derivatives. Excellent yields are obtain
Raders, Steven M.,Moore, Jane N.,Parks, Jacquelynn K.,Miller, Ashley D.,Lei?ing, Thomas M.,Kelley, Steven P.,Rogers, Robin D.,Shaughnessy, Kevin H.
p. 4649 - 4664
(2013/06/27)
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