- Intramolecular Diels-Alder Reactions of Internally-substituted Trienylsulfones. Synthesis of Bicyclo and - Systems Possessing a Bridgehead Sulfonyl Group
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A series of trienes possessing internally-activated vinylic sulfone dienophilic groups undergo intramolecular Diels-Alder (IMDA) reaction with high or complete selectivity for the cis-fused products.Incorporation of silyloxy groups within the carbon tethe
- Clasby, Martin C.,Craig, Donald,Slawin, Alexandra M. Z.,White, Andrew J. P.,Williams, David J.
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p. 1509 - 1532
(2007/10/02)
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- Intramolecular Diels-Alder Reactions of Sulphonyl-substituted Trienes. Stereospecific Formation of cis-Fused Bicyclo and - Systems Possessing a Bridgehead Sulphonyl Group
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The synthesis and thermal intramolecular Diels-Alder reactions of (E)-2-(phenylsulphonyl)-1,6,8-nonatriene 1, (E)-2-(phenylsulphonyl)-1,7,9-decatriene 2, (2E,7E)-3-(phenylsulphonyl)-2,7,9-decatriene 3, and (2E,8E)-3-(phenylsulphonyl)-2,8,10-undecatriene 4
- Clasby, Martin C.,Craig, Donald
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p. 3813 - 3814
(2007/10/02)
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