Amination of Arenes with Electron-Deficient Azodicarboxylates
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Mitchell, Helen,Leblanc, Yves
p. 682 - 687
(2007/10/02)
Synthesis of aromatic amines from electron-rich arenes and bis(2,2,2-trichloroethyl) azodicarboxylate
Electron-rich arenes react with bis(2,2,2-trichloroethyl) azodicarboxylate in 3 M lithium perchlorate-diethylether or acetone solution to produce para-substituted aryl hydrazides in high yields. The corresponding aromatic amines are readily obtained by reducing the hydrazides with zinc in acetic acid.
Zaltsgendler,Leblanc,Bernstein
p. 2441 - 2444
(2007/10/02)
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