The mechanism of the tertiary amine catalysed isomerisation of endoperoxides to hydroxyketones: Synthesis and chemistry of the intermediate postulated in the peroxide attack mechanism
Evidence is presented which demonstrates that the Kornblum-DeLaMare rearrangement does not proceed via nucleophilic attack of the peroxide linkage.
Kelly, David R.,Bansal, Harjinder,Morgan
p. 9331 - 9333
(2007/10/03)
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