Gas-Phase Reactions of O- and O2- with a Variety of Halogenated Compounds
The flowing afterglow technique has been applied to a comparative study, for a series of halogenated compounds, of dissociative attachment and reaction with O- and O2-.The ion product spectrum produced by reaction with O- and O2- overlaps but is more diverse than that obtained by dissociative attachment.Absolute rate constants for the O- and O2- reactions are reported.A few reactions, for which exothermic mechanisms can be written, were found to be quite inefficient.
Streit, Gerald E.
p. 2321 - 2324
(2007/10/02)
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