- THE PREPARATION AND TIN-119 MOESSBAUER SPECTRA OF ANIONIC ORGANOPENTAHALOGENO- AND TETRAHALOGENO-STANNATE(IV) COMPLEXES
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A series of anionic monoorgano-pentahalogenostannate(IV) complexes, M2+2-, where M = K+, Me4N+, Et4N+ or MePPh3+; X = F, Cl or Br; R = Bu, Ph or R'OCOCH2CH2 (R' = Me or Et), has been prepared and these compounds have been studied by 119mSn Moessbauer spectroscopy.The novel mono-organo-tetrachlorostannate salts, Me4N+-, where R' = Et, R, i-Pr or Bu, have been synthesised and their infrared spectra indicate that the carbonyl group is coordinated to tin, thereby completing an octahedral configuration about the metal.When R' = Et, the pentachlorostannate salt, (Me4N)2+2-, containing a free carbonyl group, could also be isolated, whilst with the weaker electron donating methyl group, only the pentachlorostannate complex was formed.
- Hobbs, Lindsey A.,Smith, Peter J.
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- Easy general method for interhalide conversions in organotin compounds
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The halides in organotin halides are easily interconverted in excellent yields using aqueous ammonium halide solutions and various organic solvents.
- Zobel, Bernhard,Lim, Allan E. K.,Dunn, Kerri,Dakternieks, Dainis
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p. 4889 - 4890
(2008/10/08)
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