Preparation of hydantoins by catalytic oxidative carbonylation of α-amino amides
(Chemical Equation Presented) Hydantoins can be synthesized from the corresponding amino amides employing oxidative catalytic carbonylation using W(CO)6 as the catalyst, I2 as the oxidant,COas the carbonyl source, andDBUas base. Secondary amides afford the hydantoins in good to excellent yields, which decrease as the steric bulk of the N-alkyl substituent increases. 2009 American Chemical Society.
Dumbris, Seth M.,Diaz, Delmy J.,McElwee-White, Lisa
experimental part
p. 8862 - 8865
(2010/03/02)
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