Hydroperoxides as Pseudohalides: Oxidation, Oxidative Alkylation, Acylation and Arylation of Acrylonitrile
New general syntheses, based on free-radical oxidative alkylation, acylation and arylation of acrylonitrile, in the presence of ButO2H, are reported; the concept of the peroxy group as a pseudohalide is suggested to explain these new reactions.
Araneo, Silvia,Fontana, Francesca,Minisci, Francesco,Recupero, Francesco,Serri, Anna
p. 1399 - 1400
(2007/10/02)
New Syntheses of Mixed Peroxides under Gif-Barton Oxidation of Alkylbenzenes, Conjugated Alkenes and Alkanes; a Free-radical Mechanism
Syntheses of mixed peroxides are performed under Gif oxidation of alkylaromatics, electron-rich conjugated alkenes (styrene, α-methylstyrene) or cyclohexane and acrylonitrile; chemical and kinetic evidence support a free-radical redox chain mechanism.
Minisci, Francesco,Fontana, Francesca,Araneo, Silvia,Recupero, Francesco
p. 1823 - 1824
(2007/10/02)
More Articles about upstream products of 158750-03-9