COMPETITIVE DIRADICAL AND DIAZOALKANE FORMATION IN THE THERMOLYSIS AND PHOTOLYSIS OF THE AZOALKANE 7,7,8-TRIMETHYL-2,3-DIAZATRICYCLO4,8>NON-2-ENE
On laser photolysis of azoalkane 1 at elevated temperature, besides the expected denitrogenation into the tricyclane 3 via 1,3-diradical 2, the diazolkane 7 is directly observed, denitrogenating into vinylcyclopentene 5.
Adam, Waldemar,Gillaspey, William D.
p. 1699 - 1702
(2007/10/02)
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