- L'electrosynthese, une alternative pour la synthese de polycarbosilanes
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The electrochemical reduction of chloromethyldimethylchlorosilane affords polycarbosilanes in high yields and this route constitutes a competitive route to 1,1,3,3-tetramethyl-1,3-disilacyclobutane formed in 34percent crude yield.The solvent mixture was varied to yield its precursor, Cl(CH2SiMe2)2Cl, in 43percent yield after distillation, while electrosynthesis in the presence of dimethyldichlorosilane provided bis(dimethyl-chlorosilyl)methane, another polycarbosilane precursor, in 60percent yield after distillation.
- Bordeau, M.,Biran, C.,Pons, P.,Leger, M.-P.,Dunogues, J.
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p. C21 - C24
(2007/10/02)
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