Copper-catalyzed oxidative α-alkylation of α-amino carbonyl compounds with ethers via dual C(sp3)-H oxidative cross- coupling
A novel copper-catalyzed oxidative alkylation of α-amino carbonyl compounds with ethers has been established for the selective synthesis of α-etherized α-amino carbonyl compounds. This oxidative alkylation is achieved by dual C(sp3)-H bond oxidative cross-coupling, and its scope is expanded to α-amino ketones, α-amino esters and α-amino amides.
Wei, Wen-Ting,Song, Ren-Jie,Li, Jin-Heng
supporting information
p. 1703 - 1707
(2014/06/09)
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